Development of a Novel Heat Treatment Method to Achieve a Fine-grained Near Lamellar Microstructure in Ti-48Al-2Cr-2Nb Intermetallic

Document Type : Manufacturing and Production

Authors

1 Ph.D. Student, Faculty of Materials and Manufacturing Technologies, Malek-e-Ashtar University of Technology, Tehran, Iran

2 Corresponding author: Associate Professor, Faculty of Materials and Manufacturing Technologies, Malek-e-Ashtar University of Technology, Tehran, Iran

3 Associate Professor, Faculty of Metallurgy and Material Engineering, Hamedan University of Technology, Hamedan, Iran

Abstract

The aim of the current research is to achieve a fine grain structure (less than 200 micrometers) in Ti-48Al-2Cr-2Nb Intermetallic by a three-step heat treatment and to investigating the parameters affecting this process. For this purpose, after the homogenization at 1175 C for 24 hours for eliminating the cast structure, three-stage heat treatment including the first stage (single-phase annealing at 1400 C for one hour with cooling in furnace and air environments), the second stage (cyclic operations including repeated heating up to 1400 C for three, five and ten cycles and cooling in air and water environments) and the third stage (Two-phase annealing at temperatures of 1175, 1225 and 1275 C  for one hour) was performed. Finally, single-phase annealing at 1400°C for one hour and cooling in the furnace, then cyclic heat treatment with five cycles at the same temperature with cooling in air and annealing at 1225°C for one hour is suggested as the optimal process to create a semi-lamellar structure with the smallest colony size.

Highlights

  • Three-stage heat treatment
  • First step: single-phase annealing at 1400 °C for one hour and cooling in the furnace.
  • Second stage: Cyclic heat treatment (five cycles) and cooling in air
  • Third step: annealing at 1225°C for one hour and cooling in air

Keywords

Main Subjects



Smiley face

[1] Appel F, Brossmann U, Christoph U, Eggert S, Janschek P, Lorenz U, et al. Recent Progress in the Development of Gamma Titanium Aluminide Alloys. Advance Engineering Materials. 2000;3:699-720 DOI 10.1002/1527-2648(200011)2:11<699::AID-ADEM699>3.0.CO;2-J##.
[2] Bewlay BP, Nag S, Suzuki A, Weimer MJ. TiAl alloys in commercial aircraft engines. Materials at High Temperatures. 2016;33:549-59 DOI 10.1080/09603409.2016.1183068##.
[3] Clemens H, Mayer S. Advanced Intermetallic TiAl Alloys. Materials Science Forum. 2017;879:113-8 DOI 10.4028/www.scientific.net/MSF.879.113##.
[4] Clemens H, Mayer S. Design, Processing, Microstructure, Properties, and Applications of Advanced Intermetallic TiAl Alloys. Advance Engineering Materials. 2013;15(4):191-215 DOI 10.1002/adem.201200231##.
[5] Ramanujan RV. Phase transformations in γ based titanium aluminides. International Materials Reviews. 2000;45(6):217-40 DOI 10.1179/095066000101528377##.
[6] Tan Y, Wang Y, You X, Liu H, Li P. Effect of Solution Heat Treatment on the Microstructure and Hardness of theTi-48Al-2Cr-2Nb Alloy Prepared by Electron Beam Smelting. Journal of Materials Engineering and Performance. 2021;31:1387–96 DOI 10.1007/s11665-021-06231-z##.
[7] Ahmadi M, Hosseini SR, Hadavi SMM. Effects of Heat Treatment on Microstructural Modification of As-Cast Gamma-TiAl Alloy. Journal of Materials Engineering and Performance. 2016;25(6):2138-46 DOI 10.1007/s11665-016-2067-7 ##.
[8] Kothari K, Radhakrishnan R, Wereley NM. Advances in gamma titanium aluminides and their manufacturing techniques. Progress in Aerospace Sciences. 2012;55:1-16 DOI 10.1016/j.paerosci.2012.04.001##.
[9] Jian-Chao H, Shu-Long X, Tian Jing C, Xu Y-Y, Wang L-J, Jia X-P, et al. Microstructure characterization and tensile properties of a Ni-containing TiAl-based alloy with heat treatment. Rare Metals. 2016;35:26-34 DOI 10.1007/s12598-015-0626-y##.
[10] Kościelna A, Szkliniarz W. Effect of cyclic heat treatment parameters on the grain refinement of Ti–48Al–2Cr–2Nb alloy. Materials Characterization. 2009;60(10):1158-62 DOI 10.1016/j.matchar.2009.03.008##.
[11] Charpentier M, Hazotte A, Daloz D. Lamellar transformation in near-Gamma TiAl alloys—Quantitative analysis of kinetics and microstructure. Materials Science and Engineering A. 2008;491:321-30 DOI 10.1016/j.msea.2008.02.009##.
[12] Gao Z, Yang J, Wu Y, Hu R, Kim S-L, Kim Y-W. A Newly Generated Nearly Lamellar Microstructure in Cast Ti-48Al-2Nb-2Cr Alloy for High-Temperature Strengthening. Metallurgical and Materials Transactions A. 2019;50:5839–52 DOI  10.1007/s11661-019-05491-8##.
[13] Rezaei H, Morakabati M, Momeni A. Evaluation of the Effect of Heat Treatment on Structural Changes and Mechanical Properties of Ti-48Al-2Cr-2Nb Intermetallic. Founding Research Journal. 2022;6(2):125-32 DOI 10.22034/FRJ.2023.384529.1173##.
[14] Shih D, Scarr G. High-Temperature Deformation Behavior of the γ Alloy Ti-48Ai-2Cr-2Nb. MRS Online Proceedings Library. 1990;213:727-32##.
[15] Leyens C, Peters M. Titanium and titanium alloys - Fundamentals and applications: Wiley‐VCH Verlag GmbH & Co. KGaA; 2003 DOI 10.1002/3527602119##.
[16] Semiatin SL, Seetharaman V, Weiss I. Hot workability of titanium and titanium aluminide alloys—an overview. Materials Science and Engineering A. 1998;243:1-24 DOI 10.1016/S0921-5093(97)00776-4##.
[17] Wang JN, Yang J, Xia Q, Wang Y. On the grain size refinement of TiAl alloys by cyclic heat treatment. Materials Science and Engineering A. 2002;329:118-23 DOI 10.1016/S0921-5093(01)01543-X##.
[18] Cupid D. Thermodynamic Assessment of the Ti-al-nb, Ti-al-cr, and Ti-al-mo Systems Gainesville: University of Florida; 2009 DOI 10.3139/146.110015##.
[19] Appel F, Oehring M, Wagner R. Novel design concepts for gamma-base titanium aluminide alloys. Intermetallics. 2000;8((9-11)):1283-312 DOI 10.1016/S0966-9795(00)00036-4##.
[20] Huang L. Microstructural Control and Alloy Design of the Ti-Al-Nb-W-B Alloys Knoxville university of Tennessee; 2008 DOI 10.1007/s11661-007-9113-x##.
[21] Szkliniarz A. Grain Refinement of Ti-48Al-2Cr-2Nb Alloy by Heat Treatment Method. Solid State Phenomena. 2012;191:221-34 DOI 10.4028/www.scientific.net/ssp.191.221##.
[22] Yim S, Bian H, Aoyagi K, Chiba A. Effect of multi-stage heat treatment on mechanical properties and microstructure transformation of Ti–48Al–2Cr–2Nb alloy. Materials Science and Engineering: A. 2021;816 DOI 10.1016/j.msea.2021.141321##.
[23] Bibhanshu N, Suwas S. Globularisation of α2 phase in (α2 + γ) two-phase lamellar titanium aluminide by thermal cycling. Materials Letters. 2021;292:1-4 DOI 10.1016/j.matlet.2021.129617##.
[24] Voort GFV. Handbook metallography and microstructurs USA: ASM International; 2004 DOI 10.31399/asm.hb.v09.a0003800##.
[25] ASTM E 112: Standard test methods for determining average grain size. 2004##.
[26] Cao S, Xiao S, Chen Y, Xu L, Wang X, Han J, et al. Phase transformations of the L12-Ti3Al phase in γ-TiAl alloy. Materials & Design. 2017;121:61-8 DOI 10.1016/j.matdes.2017.02.047.##.
[27] Maruyama K, Yamaguchi M, Suzuki G, Zhu H, Kim HY, Yoo MH. Effects of lamellar boundary structural change on lamellar size hardening in TiAl alloy. Acta Materialia. 2004;52(17):5185-94 DOI 10.1016/j.actamat.2004.07.029##.
[28] Humphreys FJ, Hatherly M. Recrystallization and Related Annealing Phenomena. second ed: Elsevier; 2004##.
[29] Franzén SF, Karlsson J. Titanium Aluminide Manufactured by Electron Beam Melting. Gothenburg, Sweden: Chalmers University of Technology; 2010 DOI  20.500.12380/127716##.
Volume 20, Issue 3 - Serial Number 77
Serial No. 77, Summer
November 2024
Pages 47-57
  • Receive Date: 03 May 2024
  • Revise Date: 23 May 2024
  • Accept Date: 01 June 2024
  • Publish Date: 21 November 2024